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Justify that alkanes give substitution reactions.

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Answer. Alkanes give only substitution reactions. A reaction in which one or more hydrogen atoms of a saturated compound are replaced with some other atoms like halogen is called a substitution reaction. For example in diffused sunlight one hydrogen atom of CH4 is replaced by halogen atom to produce chloromethane.
                          diffused sunlight
               CH4 + C12 ——————> CH3C1 + HC1
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