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What are the scales of temperature?

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Temperature is usually measured in two different scales:

1-Celsius scale

2-Fahrenheit sclae

Scale of temperature is a way to measure temperature quantitatively. Empirical scales measure the quantity of heat in a system in relation to a fixed parameter, a thermometer. They are not absolute measures, that is why scales vary. Absolute temperature is thermodynamic temperature because it is directly related to thermodynamics. It is the Zeroth Law of Thermodynamics that leads to a formal definition of thermodynamic temperature.

Formal description

According to the zeroth law of thermodynamics, being in thermal equilibrium is an equivalence relation. Thus all thermal systems may be divided into a quotient set by this equivalence relation, denoted below as M. Assume the set M has the cardinality of c, then one can construct an injective function ƒ: M → R , by which every thermal system will have a number associated with it such that when and only when two thermal systems have the same such value, they will be in thermal equilibrium. This is clearly the property of temperature, and the specific way of assigning numerical values as temperature is called a scale of temperature.[1][2][3] In practical terms, a temperature scale is always based on usually a single physical property of a simple thermodynamic system, called a thermometer, that defines a scaling function mapping the temperature to the measurable thermometric parameter. Such temperature scales that are purely based on measurement are called empirical temperature scales.

The second law of thermodynamics provides a fundamental, natural definition of thermodynamic temperature starting with a null point of absolute zero. A scale for thermodynamic temperature is established similarly to the empirical temperature scales, however, needing only one additional fixing point.

Empirical scales

Empirical scales are based on the measurement of physical parameters that express the property of interest to be measured through some formal, most commonly a simple linear, functional relationship. For the measurement of temperature, the formal definition of thermal equilibrium in terms of the thermodynamic coordinate spaces of thermodynamic systems, expressed in the zeroth law of thermodynamics, provides the framework to measure temperature.

All temperature scales, including the modern thermodynamic temperature scale used in the International System of Units, are calibrated according to thermal properties of a particular substance or device. Typically, this is established by fixing two well-defined temperature points and defining temperature increments via a linear function of the response of the thermometric device. For example, both the old Celsius scale and Fahrenheit scale were originally based on the linear expansion of a narrow mercury column within a limited range of temperature,[4] each using different reference points and scale increments.

Different empirical scales may not be compatible with each other, except for small regions of temperature overlap. If an alcohol thermometer and a mercury thermometer have same two fixed points, namely the freezing and boiling point of water, their reading will not agree with each other except at the fixed points, as the linear 1:1 relationship of expansion between any two thermometric substances may not be guaranteed.

Empirical temperature scales are not reflective of the fundamental, microscopic laws of matter. Temperature is a universal attribute of matter, yet empirical scales map a narrow range onto a scale that is known to have a useful functional form for a particular application. Thus, their range is limited. The working material only exists in a form under certain circumstances, beyond which it no longer can serve as a scale. For example, mercury freezes below 234.32 K, so temperature lower than that cannot be measured in a scale based on mercury. Even ITS-90, which interpolates among different ranges of temperature, has only a range of 0.65 K to approximately 1358 K (−272.5 °C to 1085 °C).

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